Preparation and Characterization of some Polyalkylarylamines.

Authors

A. Shaaban, Department of Chemistry., Faculty of Science., Zagazig University (Benha Branch)., Benha., Egypt.
M. El-Komy, Department of Physical and Mathematical Science., Faculty of Engineering (Shoubra)., Zagazig University., (Benno Branch., Cairo., Egypt.
A. Al-Sarwy, Department of Physical and Mathematical Science., Faculty of Engineering (Shoubra)., Zagazig University., (Benno Branch., Cairo., Egypt.
I. Rashed, Associate Professor., Department of Physical Science., Faculty of Engineering., Mansoura University., El-Mansoura., Egypt.

Corresponding Author

Rashed, I.

Subject Area

Mathematics and Engineering Physics

Article Type

Original Study

Abstract

Adducts of polyalkylarylamines will stoichiometric amounts of stannous chloride were obtained by the reaction of 1,2-dichloroethane with m-phenylenediamine, p-phenylenediamine and 4,4 diaminodiphenyl in the presence of hydrochloric acid and stoichiometric amounts of stannous chloride in methanol as a solvent. Also, adduct of poly (chloromethyne-co- 4,4-dianiinodiphenyl) was obtained from the reaction of chloroform and benzidine by similar method. The structure of these adducts was confirmed by JR spectroscopy, as well 0.X-ray diffractometery, These adducts when reacted with aqueous solution of ammonium carbonate gave the corresponding polyalkylaryl-amine hydrochlorides. Also thermal analysis of these adducts were carried out .

Recommended Citation

Shaaban, A.; El-Komy, M.; Al-Sarwy, A.; and Rashed, I. (2021) "Preparation and Characterization of some Polyalkylarylamines.," Mansoura Engineering Journal: Vol. 13 : Iss. 2 , Article 18.
Available at: https://doi.org/10.21608/bfemu.2021.173266