Solvent Extraction of Zinc(II) and Manganese(II) with 5,10,15,20-Tetraphenyl-21H,23H-Porphine (TPP) through the Metal Exchange Reaction of LEAD(II)-TPP.

Authors

Seham Nagib, Academy of Special Studies, Worker University, EgyptFollow

Corresponding Author

Nagib, Seham

Subject Area

Mechanical Power Engineering

Article Type

Original Study

Abstract

An investigation was carried out on the extraction of aqueous Zn(II) and Mn(π) with a hydrophobic porphyrin (5,10,15,20-tetraphenyl-21H,23H porphine, TPP) through a metal exchange reaction of Pb(π)-TPP. The distribution ratios (D) of these metals were found to be independent of the Pb(π) concentration in the aqueous phase. Pb(π) in the aqueous phase acted as a catalyst which promoted the metal-TPP complexation.

Keywords

Zn(π); Mn(π); TPP; metal exchange; Pb(π)

Recommended Citation

Nagib, Seham (2020) "Solvent Extraction of Zinc(II) and Manganese(II) with 5,10,15,20-Tetraphenyl-21H,23H-Porphine (TPP) through the Metal Exchange Reaction of LEAD(II)-TPP.," Mansoura Engineering Journal: Vol. 32 : Iss. 2 , Article 18.
Available at: https://doi.org/10.21608/bfemu.2020.128551